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蔡格梅

领域:新材料产业 学校:中南大学职称:

高性能合金和氧化物功能材料的相图测定、晶体结构解析与性能研究

主持、参与国家级科研项目情况:
国家重点研发计划子课题, 2018YFE0306101,ODS低活化钢和铜合金成分及组织结构优化设计,2019/01-2023/12,在研
国家自然科学基金面上项目,51772330,新型磷酸盐发光材料的晶体结构、电子结构与量子效率和热稳定性关系研究,2018/01-2021/12,在研
国家重点研发计划子课题, 2016YFB0701301,航空用先进钛基合金集成计算设计与制备,2016/07-2020/6,在研
国家自然科学基金面上项目,51472273,新型碱土硼酸盐基荧光粉的制备及其发光性能调控机理研究,2015/01-2018/12,在研
国家重点基础研究发展计划(973计划)子课题, 2014CB644002-1,钛合金高通量实验测试方法,2014/01-2018/7,结题
国家自然科学基金青年项目,51002189,MxO-In2O3-B2O3(M=Ca,Li)体系相图、结构与性能,2011/01-2013/12,结题




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教育背景

工作经历

项目课题经历

论文、成果、著作等

学术论文发表

第一作或通讯:

[34] Liumei Su, Xing Fan, Yijia Liu, Zhanchao Wu, Gemei Cai*, Xiaojun Wang*, Structure and Luminescent Properties of New Dy3+/Eu3+/Sm3+-activated InNbTiO6 Phosphors for White UV-LEDs, Optical Materials, 2019, 98: 109403.

[33] T. Hu, Y. Zeng, X.M. Huang, G.M. Cai*, Y.H. He, Z.P. Jin, Experimental investigation of phase relationship in Ti-Fe-Hf ternary system, Calphad, 2019, 67: 101669.

[32] J. Zhang, Z.Y. Ma, J.G. Guo, G.M. Cai*, L. Ma, X.J. Wang**, Red-green-blue-tunable emission from Eu3+ and Tb3+ codoped pyrophosphate phosphors, J. Lumin., 2019, 215: 116732.

[31] G.X. Zhang, J. Zhang, Y.J. Liu, J.Y. Si, X.M. Tao, G.M. Cai*, Structure and luminescence properties of multicolor phosphors with excellent thermal stability based on a new phosphate Ba3In4(PO4)6, J. Alloys Compd., 2019, 797: 775-785.

[30] X.M. Huang, T. Hu, S.H. Liu, G.M. Cai*, Y.H. He, Z.P. Jin, Experimental investigation of phase equilibria in the Tb-Si-Cr system, Calphad, 2019, 65: 212-224.

[29] Jin Chen, Wenhua Xue, Shan Li, Gengxin Zhang, Gemei Cai*, and Huaizhou Zhao*, Enhanced thermoelectric properties in N-type Mg2Si0.4-xSn0.6Sbx synthesized by alkaline earth metal reduction, RSC Adv., 2019, 9: 4008-4014.

[28] L.L. Zhu, Z.Q. Chen, W. Zhong, C.D. Wei, G.M. Cai*, L. Jiang, Z.P. Jin, J.C. Zhao*, Measurement of Diffusion Coefficients in the bcc Phase of the Ti-Sn and Zr-Sn Binary Systems, Metallurgical and Materials Transactions A, 2019, 50: 1409-1420.

[27] J. Zhang, G.X. Zhang, G.M. Cai *, Z.P. Jin, Reduction of Ce(IV) to Ce(III) Induced by Structural Characteristics and Performance Characterization of Pyrophosphate MgIn2P4O14-based Phosphors, J. Lumin., 2018, 203: 590-598.

[26] X.M. Huang, W.J. Zeng, J.L. Liu, G.M. Cai *, S.H. Liu, H.S. Liu, Z.P. Jin, Experimental investigation and thermodynamic calculation of Ti-Co-Hf system, CALPHAD, 2018, 62: 128-140.

[25] J. Zhang, G.M. Cai *, G.X. Zhang, Z.P. Jin, Insight into crystal structure and Eu/Tb doped luminescence property of a new phosphate, J. Alloys Compd., 2018, 762: 44-455.

[24] H. Pei, L.M. Su, G.M. Cai*, Z.P. Jin, Modification of YNbO4 and YNbTiO6 photoluminescence by nitrogen doping, AIP Advances, 2018, 8: 04517.

[23] J.L. Liu, X.M. Huang, G.H. Li, G.M. Cai*, H.S. Liu, Z.P. Jin, Experimental investigation on phase equilibria of Cu-Ti-Hf system and performance of Cu(Ti, Hf)2 phase, Journal of Materials Science, 2018, 53: 7809-7821.

[22] Z.X. Wang, H. Pei, X.M. Tao, G.M. Cai*, R.H. Mao, Z.P. Jin, Enhanced scintillation of Ba3In(B3O6)3 based on nitrogen doping, J. Solid State Chem., 2018, 258: 351-357.

[21] J. Zhang, G.M. Cai*, L.W. Yang, Z.Y. Ma, Z.P. Jin, Layered Crystal Structure, Color-Tunable Photoluminescence, and Excellent Thermal Stability of MgIn2P4O14 Phosphate-Based Phosphors, Inorg. Chem., 2017, 56, 12902-12913.

[20] J.L. Liu, L.L. Zhu, X.M. Huang, G.M. Cai*, Z.P. Jin, Investigation of the phase equilibria in Ti-Ni-Hf system using diffusion triples and equilibrated alloys, CALPHAD, 2017, 58: 160-168.

[19] L.M. Su, X. Fan, G.M. Cai*, Z.P. Jin*, A Peculiar Layered 12-fold Cationic Coordination Compound LiInTi2O6: Phase Relations, Crystal Structure and Color-tunable Photoluminescence, RSC Advances, 2017, 7: 22156-22169.

[18] G.M. Cai*, N. Yang, H.X. Liu, J.Y. Si, Y.Q. Zhang, Single-phased and color tunable LiSrBO3:Dy3+, Tm3+, Eu3+ phosphors for white-light-emitting application, J. Lumin., 2017,187:211-220.

[17] J. Zhang, X.M. Tao, G.M. Cai*, Z.P. Jin, Phase relation, structure, and properties of borate MgYB5O10 in MgO-Y2O3-B2O3 system, Powder Diffr., 2017, 32: 97-106.

[16] Y. Zeng, L.L. Zhu, G.M. Cai*, H.S. Liu, J.W. Huang*, Z.P. Jin, Investigation of phase equilibria in the Ti-Co-Zr ternary system, CALPHAD, 2017, 56: 260-269.

[15] L.L. Zhu, Q.F. Zhang, Z.Q. Chen, C.D. Wei, G.M. Cai*, L. Jiang, Z.P. Jin, J.C. Zhao*, Measurement of interdiffusion and impurity diffusion coefficients in the bcc phase of the Ti-X (X = Cr, Hf, Mo, Nb, V, Zr) binary systems using diffusion multiples, J. Mater. Sci., 2017, 52: 3255-3268.

[14] X.M. Huang, L.L. Zhu, G.M. Cai*, H.S. Liu, Z.P. Jin*, Experimental investigation of phase equilibria in the Ti-Al-Mo ternary system, J. Mater. Sci., 2017, 52: 2270-2284.

[13] X. Fan, L.M. Su, G.M. Cai*, H.S. Liu, Z.P. Jin*, Experimental determination and thermodynamic calculation of BaO-In2O3-B2O3 system, CALPHAD, 2016, 55: 281-293.

[12] L.M. Su, X. Fan, G.M. Cai*, Z.P. Jin*, Tunable luminescence properties and energy transfer of Tm3+, Dy3+, and Eu3+ co-activated InNbO4 phosphors for warm-white-lighting, Ceram. Int., 2016, 42: 15994-16006.

[11] Z.X. Wang, H.K. Li, G.M. Cai*, Z.P. Jin, Synthesis, crystal structure, and thermal stability of new borates Na3REB2O6 (RE = Pr, Sm, Eu), Powder Diffr., 2016, 31: 1-8.

[10] X. Fan, L.M. Su, G.M. Cai*, H.S. Liu, Z.P. Jin*, Thermal stability, phase transition mechanism and primary crystal region determination of scintillating material Ba3InB9O18 in BO1.5-BaO-InO1.5 system, J. Alloys Compd., 2016, 658: 608-615.

[9] G.M. Cai*, H.X. Liu, J. Zhang, Y. Tao, Z.P. Jin, Luminescent properties and performance tune of novel red-emitting phosphor CaInBO4: Eu3+, J. Alloys Compd., 2015, 650: 494-501.

[8] L.M. Su, X. Fan, G.M. Cai*, H.S. Liu, Z.P. Jin, Phase relations, crystal structure, and phase transformation of In1-xNb1-xTi2xO4 (0<x<0.45) in the In2O3-Nb2O5-TiO2 system, J. Alloys Compd., 2015, 651: 97-105.

[7] G.M. Cai*, L. Wang, L.M. Su, H.S. Liu, and Z.P. Jin, Subsolidus phase relations in CoO–In2O3–B2O3 system and crystal structure of Co3-xInxBO5 solid solution for 0<X<1, J. Alloys Compd., 2014, 615: 809-816.

[6] G.M. Cai*, J.J. Fan, H.K. Li, Z. Zhao, L.M. Su, and Z.P. Jin, Synthesis and relative optical properties of Eu3+/Tb3+-activated Li3InB2O6, J. Alloys Compd., 2013, 562: 182-186.

[5] H.K. Li, G.M. Cai*, J.J. Fan, Z.P. Jin, T.T. Zhou, and X.L. Chen, Crystal structures of two novel borate compounds MgInBO4 and MgIn7/8B7/8O29/8, J. Solid State Chem., 2013, 202: 262-268.

[4] H.K. Li, L. Wang, G.M. Cai*, J.J. Fan, X. Fan, and Z.P. Jin, Synthesis and crystal structure of a novel ludwigite borate: Mg2InBO5, J. Alloys Compd., 2013, 575: 104-108.

[3] H.K. Li, G.M. Cai*, J.J. Fan, and Z.P. Jin, Subsolidus phase relations in CaO-In2O3-B2O3 system and crystal structure of CaInBO4, J. Alloys Compd., 2012, 516: 107-112.

[2] G.M. Cai*, Yu Sun, H.K. Li, X. Fan, X.L. Chen, F. Zheng, and Z.P. Jin*, Crystal structure and photoluminescence of Tb3+-activated Ba3InB3O9, Mater. Chem. Phys., 2011, 129: 761-768.

[1] G.M. Cai*, X.M. Tao, L.M. Su, F. Zheng, D.Q. Yi, X.L. Chen, and Z.P. Jin*, Structure, thermal stability and properties of Li3Sc(BO3)2, J. Solid State Chem., 2011, 184: 115-122.

第二通讯或合作:

[17] S.Y. Song, J.Y. Si*, J. Zhang, G.M Cai*, Structure, tunable luminescence and energy transfer in Tb3+ and Eu3+ codoped Ba3InB9O18 phosphors. RSC Advances, 2019, 9: 1029-1035.

[16] J.Y. Si, L. Wang*, L.H. Liu, W. Yi, G.M. Cai, T. Takeda, S. Funahashi, N. Hirosaki, R.J. Xie*, Structure, luminescence and energy transfer in Ce3+ and Mn2+ codoped γ-AlON phosphors, J. Mater. Chem. C., 2019, 7: 733-742.

[15] M. Li, Y. Luo, G.M. Cai, X. Li, X.Y. Li, Z.K. Han*, X.Y. Lin, D. Sarker, J.L. Cui*, Realizing high thermoelectric performance in Cu2Te alloyed Cu1.15In2.29Te4, Journal of Materials Chemistry A, 2019, 7: 2360-2367.

[14] K. Xu, S.H. Liu, Y. Du, L.Y. Dreval, G.M. Cai, Z.P. Jin, Thermodynamic investigation of the Mg-Ni-Zn system by experiments and calculations and its application, Journal of Alloys and Compounds, 2019, 784: 769-787.

[13] J. Y. Si*, S. Y. Song, N. Liu, G.M. Cai*, L.M. Su, Synthesis and photoluminescence of host-sensitized MgNb2O6 based phosphors, Journal of Luminescence, 2018, 198: 10-18.

[12] J.L. Cui*, G.M. Cai*, W. Ren, Increased effective mass and carrier concentration responsible for the improved thermoelectric performance of the nominal compound Cu2Ga4Te7 with Sb substitution for Cu, RSC advances, 2018, 8: 21637.

[11] J.Y. Si*, N. Liu, S.Y. Song, G.M. Cai**, N. Yang, Z. Li, Investigation on Eu/Tb activated photoluminescent properties of Li3Sc(BO3)2 based phosphors, J. Alloys Compd., 2017, 719: 171-181.

[10] J.H. Zhu, Y. Luo, G.M. Cai, X.L. Liu, Z.L. Du, F.L. Tang, J.L. Cui, Significant improvement in the thermoelectric performance of Sb-incorporated chalcopyrite compounds Cu18Ga25SbxTe50-x (x=0–3.125) through the coordination of energy band and crystal structures, J. Mater. Chem. A, 2017, 5: 24199.

[9] N. Liu, J.Y. Si*, G.M. Cai**, Y. Tao, Crystal structure, luminescent properties and energy transfer of Eu3+/Dy3+ doped GdNbTiO6 broad band excited phosphors, RSC Advances, 2016, 6:50797.

[8] H. Li, G.M. Cai, W.J. Wang, Room temperature luminescence and ferromagnetism of AlN:Fe, AIP Advances, 2016, 6: 065025.

[7] H. Li, G.M. Cai, B. Song, A facile method for synthesis of Mg0.87Cu0.13O and its magnetic properties, Materials Chemistry and Physics, 2016, 182: 445-449.

[6] X.Y. Chang, J.K. Jian, G.M. Cai, R. Wu, J. Li, Three-Dimensional FeSe2 Microflowers Assembled by Nanosheets: Synthesis, Optical Properties, and Catalytic Activity for the Hydrogen Evolution Reaction, Electron. Mater. Lett., 2016, 12: 237-242.

[5] H. Li, B. Song, G.M. Cai, Synthesis of Ni1-xZnxO hollow structures by a facile method, Physica E, 2015, 66: 257-262.

[4] Z.Y. Xie, K.L. Lv, H.S. Liu, G.M. Cai, Z.P. Jin, Experimental investigation of phase equilibria in Cu-Ge-Ti system, J. Alloys Compd., 2015, 651: 590-597.

[3] L.H. Huang, Q. Chen, Y. He, X.M. Tao, G.M. Cai, H.S. Liu, Z.P. Jin, Thermodynamic modeling of Fe-Ti-Bi system, CALPHAD, 2014, 46: 34-41.

[2] F. Yang, F.H. Xiao, S.G. Liu, S.S. Dong, L.H. Huang, Q. Chen, G.M. Cai, H.S. Liu, Z.P. Jin, Isothermal section of Al-Ti-Zr ternary system at 1273 K, J. Alloys Compd., 2014, 585: 325-330.

[1] J. Liu, S.S. Tang, Y.K. Lu, G.M. Cai, S.Q. Liang, W.J. Wang, and X.L. Chen, Synthesis of Mo2N Nanolayer Coating MoO2 Hollow Nanostructures as High-Performance Anode Materials for Lithium-Ion Batteries, Energy Environ. Sci., 2013, 6: 2691-2697.

专利申报和授权:

[1] 蔡格梅、汪志勋、樊星、刘华山、金展鹏,一种硼酸盐闪烁材料,中国发明专利,专利号201510416971.9.

[2] 蔡格梅、刘红星、刘华山、金展鹏,一种稀土硼酸盐基红色荧光粉,中国发明专利,专利号201510295407.06.

[3] 蔡格梅、张静、司家勇、金展鹏,一种稀土荧光粉用镁铟磷酸盐基质材料及其制备方法,中国发明专利,专利号201610235386.3.

[4] 蔡格梅、苏柳梅、樊星、金展鹏,一种稀土荧光粉用钛酸盐基质材料及其制备方法,中国发明专利,专利号201610200664.1.

[5] 蔡格梅、张静、金展鹏,一种稀土荧光粉用磷酸盐基质材料及其制备方法,中国发明专利,专利号201610153433.X.

[6] 蔡格梅、张静、金展鹏,一种红色或绿色稀土磷酸盐荧光粉材料及其制备方法,中国发明专利,专利号201610153362.3.

[7] 蔡格梅、张静、司家勇、金展鹏,一种镁铟磷酸盐红色和绿色荧光粉的制备,中国发明专利,专利号201610235078.0.

[8] 蔡格梅、苏柳梅、樊星、金展鹏,一种紫外LED激发的暖白色荧光粉,中国发明专利,专利号201610153343.0.

[9] 蔡格梅,阳念,司家勇,刘立斌。一种零掺杂稀土硼酸盐红色荧光粉制备及其在LED领域的应用, 中国发明专利,专利号2018102321289.

专利、著作版权等

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