教育背景
[1] 1992.9-1996.7
吉首大学 | 化学 | 学士学位 | 大学本科毕业
[2] 1996.9-1999.7
中南大学 | 矿物加工工程 | 硕士学位 | 硕士研究生毕业
[3] 1999.9-2004.11
中南大学 | 矿业工程 | 博士学位 | 博士研究生毕业
工作经历
[1] 1999.7-至今
化学化工学院 | 中南大学 | 教授 | 教师 |
[2] 2010.6-2014.8
化工与材料系 | University of Alberta | Visiting professor/Visiting scholar |
项目课题经历
论文、成果、著作等
1. Facile preparation of novel and active 2D nanosheets from non-layered and traditionally non-exfoliable earth-abundant materials. Journal of Materials Chemistry A. 2019.
2. Defect-rich 2D reticulated MoS2 monolayers: Facile hydrothermal preparation and marvellous photoelectric properties. Journal of the Taiwan Institute of Chemical Engineers. 2019.
3. Hetero-difunctional Reagent with Superior Flotation Performance to Chalcopyrite and the Associated Surface Interaction Mechanism. Langmuir. 2019.
4. Probing the interactions of hydroxamic acid and mineral surfaces: Molecular mechanism underlying the selective separation. Chemical Engineering Journal. 2019.
5. Novel chelating surfactant 5-heptyl-1,2,4-triazole-3-thione: Its synthesis and flotation separation of malachite against quartz and calcite. Minerals Engineering. 2018.
6. A DFT prediction on the chemical reactivity of novel azolethione derivatives as chelating agents Implications for copper minerals flotation and copper corrosion inhibition. Journal of the Taiwan Institute of Chemical Engineers. 2018.
7. Thiadiazole-thione surfactants Preparation, flotation performance and adsorption mechanism to malachite. Journal of Industrial and Engineering Chemistry. 2018.
8. 5-Heptyl-1,3,4-oxadiazole-2-thione: Synthesis and flotation mechanism to chalcopyrite. Journal of Industrial and Engineering Chemistry. 2018.
9. Cu(I)/Cu(II) mixed-valence surface complexes of S- (2-hydroxyamino)-2-oxoethyl -N,N-dibutyldithiocarbamate: Hydrophobic mechanism to malachite flotation. Journal of Colloid and Interface Science. 2018.
10. Hemimorphite Flotation with 1-hydroxydodecylidene-1,1-diphosphonic acid and Its Mechanism. Minerals.2018.
11. New advances in the understanding and development of flotation collectors: A Chinese experience. Minerals Engineering. 2018.
12. Structure-activity relationship of xanthates with different hydrophobic groups in the flotation of pyrite. Minerals Engineering. 2018.
13. The hydrophobic mechanism of di(2-ethylhexyl) phosphoric acid to hemimorphite flotation.Colloids and Surfaces a-Physicochemical and Engineering Aspects. 2018.
14. A DFT study on the structure-reactivity relationship of aliphatic oxime derivatives as copper chelating agents and malachite flotation collectors. Journal of Industrial and Engineering Chemistry. 2017.
15. Molecular design of flotation collectors: A recent progress. Advances in Colloid and Interface Science. 2017.
16. Synthesis and structural characterization of silver(I) and gold(I) complexes of N,N '-diisobutyloxycarbonyl-N '',N '''-(1,3-propylene)-bisthiourea. Polyhedron. 2017.
17. The adsorption mechanism of N-butoxypropyl-S- 2-(hydroxyimino) propyl dithiocarbamate ester to copper minerals flotation. International Journal of Mineral Processing. 2017.
18. The flotation behavior and adsorption mechanism of O-isopropyl-S- 2-(hydroxyimino) propyl dithiocarbonate ester to chalcopyrite. Journal of the Taiwan Institute of Chemical Engineers.2017.
19. The role of HABTC's hydroxamate and dithiocarbamate groups in chalcopyrite flotation.Journal of Industrial and Engineering Chemistry. 2017.
20. A novel surfactant 2-amino-6-decanamidohexanoic acid: Flotation performance and adsorption mechanism to diaspore. Minerals Engineering. 2016.
21. A novel surfactant, N,N-diethyl-N'-cyclohexylthiourea: Synthesis, flotation and adsorption on chalcopyrite. Journal of Industrial and Engineering Chemistry. 2016.
22. Adsorption of alpha-hydroxyoctyl phosphonic acid to ilmenite/water interface and its application in flotation. Colloids and Surfaces a-Physicochemical and Engineering Aspects. 2016.
23. In situ probing the self-assembly of 3-hexyl-4-amino-1,2,4-triazole-5-thione on chalcopyrite surfaces. Colloids and Surfaces a-Physicochemical and Engineering Aspects. 2016.
24. Investigation on the flotation behavior and adsorption mechanism of 3-hexyl-4-amino-1,2,4-triazole-5-thione to chalcopyrite. Minerals Engineering. 2016.
25. Investigation on the selectivity of N-((hydroxyamino)-alkyl) alkylamide surfactants for scheelite/calcite flotation separation. Journal of Industrial and Engineering Chemistry. 2016.
26. The activation mechanism of Cu(II) to ilmenite and subsequent flotation response to alpha-hydroxyoctyl phosphinic acid. Journal of Industrial and Engineering Chemistry. 2016.
27. Understanding the hydrophobic mechanism of 3-hexyl-4-amino-1, 2,4-triazole-5-thione to malachite by ToF-SIMS, XPS, FTIR, contact angle, zeta potential and micro-flotation. Colloids and Surfaces a-Physicochemical and Engineering Aspects. 2016.
28. A novel surfactant N-(6-(hydroxyamino)-6-oxohexyl)octanamide: Synthesis and flotation mechanisms to wolframite. Separation and Purification Technology. 2015.
29. Adsorption thermodynamics and kinetics of N, N'-diisopropoxypropyl-N", N'''-oxydiethylenedicarbonyl bis (thiourea) on chalcopyrite surfaces. Journal of Industrial and Engineering Chemistry. 2015.
30. Flotation behavior and adsorption mechanism of alpha-hydroxyoctyl phosphinic acid to malachite. Minerals Engineering. 2015.
31. Flotation performances and adsorption mechanism of alpha-hydroxyoctyl phosphinic acid to cassiterite. Applied Surface Science. 2015.
32. N-(6-(hydroxyamino)-6-oxohexyl) decanamide collector: Flotation performance and adsorption mechanism to diaspore. Applied Surface Science. 2015.
33. A novel collector 2-ethyl-2-hexenoic hydroxamic acid: Flotation performance and adsorption mechanism to ilmenite. Applied Surface Science. 2015.
34. Study of N-isopropoxypropyl-N'-ethoxycarbonyl thiourea adsorption on chalcopyrite using in situ SECM, ToF-SIMS and XPS. Journal of Colloid and Interface Science. 2015.
35. Gemini trisiloxane surfactant: Synthesis and flotation of aluminosilicate minerals. Minerals Engineering. 2014.
36. Investigations on reverse cationic flotation of iron ore by using a Gemini surfactant: Ethane-1,2-bis(dimethyl-dodecyl-ammonium bromide). Chemical Engineering Journal. 2014.
37. Synthesis, characterization and properties of 3,3'-diethyl-1,1'-oxydiethylenedicarbonyl bis(thiourea). Research on Chemical Intermediates. 2014.
38. The interaction of N-butoxypropyl-N'-ethoxycarbonylthiourea with sulfide minerals: Scanning electrochemical microscopy, diffuse reflectance infrared Fourier transform spectroscopy, and thermodynamics. Colloids and Surfaces a-Physicochemical and Engineering Aspects. 2014
专利、著作版权等
1) 刘广义,麻龙群,黄耀国,钟宏. 一种1,3,4-噁二唑-2-硫酮类浮选捕收剂的应用,ZL201610846837.7,2018-04-03.
(2) 刘广义,刘俊,胡哲. 一种1,2,4,5-四唑-3-硫酮类浮选捕收剂的应用,ZL201610846730.2,2018-05-11.
(3) 刘广义,黄耀国. 黄原酸盐的制备方法,ZL201510906094.3,2018-02-27.
(4) 刘广义,黄耀国,麻龙群. 一种1,3,4-噻二唑-2-硫酮类浮选捕收剂的应用,ZL201610846832.4,2018-07-17.
(5) 刘广义,肖静晶,王勇泉,钟宏,王帅,曹占芳,一种双配体捕收剂及其制备和应用,ZL201210570221.3,2014-04-02。
(6) 刘广义,钟宏,狄宁,一种硫脲化合物及其在金属矿浮选中的应用和制备,ZL201110341679.7,2013-10-23。
(7) 刘广义,钟宏,曹占芳,喻名强,一种硫脲化合物及制备和其在金属矿浮选中的应用,ZL201110341407.7,2014-11-05。
(8) 刘广义,刘胜,黄耀国. 一种具有巯基-异羟肟酸基结构的有色金属矿浮选捕收剂及其制备方法和应用,ZL201510202506.5,2017-03-01.
(9) 刘广义,曲肖彦,钟宏,刘胜,王帅,曹占芳. 一种氨基三唑类硫酮捕收剂的应用,ZL201410576691.X,2017-03-15.
(10) 刘广义,肖静晶,杨湘琳,钟宏. 一种具有巯基-肟基结构的有色金属矿浮选捕收剂及其应用, ZL201510201017.8,2017-04-19.
(11) 刘广义,张惠丽,钟宏,刘胜,赵刚,肖静晶,一种异羟肟酸或异羟肟酸盐的制备方法,ZL201410189143.1,2015-07-01。
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