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何广科

领域:新材料产业 学校:南京工业大学职称:副教授

炔烃的氟化及硼化反应...

具体了解该专家信息,请致电:027-87555799 邮箱 haizhi@uipplus.com

教育背景

* 2005/12 – 2009/12,浙江大学,理学博士 * 2002/09 – 2005/06,浙江大学,工学硕士 * 1998/09 – 2002/07,江苏石油化工学院,学士

工作经历

*2010/07–至今,南京工业大学工作

项目课题经历

* 江苏省高校自然科学基金面上项目(12KJB150011) * 江苏省青年自然科学基金(BK20140937)

论文、成果、著作等

Zhu, G.; Qiu, S.; Xi, Y.; Ding, Y.; Zhang D.; Zhang R.; He, G.*; Zhu, H*. (IPr)CuF-catalyzed α-site regiocontrolled trans-hydrofluorination of ynamides Org. Biomol. Chem., 2016, 14, 7746–7753. * He, G.; Qiu, S.; Zhu, G.; Zhang D.; Zhang R.; Zhu, H*. Cu(I)- or Ag(I)-Catalyzed Regio- and Stereocontrolled trans-Hydrofluorination of Ynamides, Org. Lett., 2016, 18, 1856–1859. * Huang, H.; Tang, L.; Yang, Z.; Liu, Q.; Xi, Y.; He, G.*, Zhu, H*. Formation of α-chalcogenyl acrylamides through unprecedented chalcogen-mediated metal-free oxyfunctionalization of ynamides with DMSO as an oxidant, Chem. Commun., 2016, 52, 5605–5608. * Huang, H.; Fan, J.; He, G.*; Yang, Z.; Jin, X.; Liu, Q.; Zhu, H*. Generation of Oxazolidine-2,4-diones Bearing Sulfur-Substituted Quaternary Carbon Atoms by Oxothiolation/Cyclization of Ynamides, Chem. Eur. J. 2016, 22, 2532–2538. * Huang, H.; Zhu, X.; He, G.*; Liu, Q.; Fan, J.; Zhu, H*. Controlled Synthesis of 1,3,5-Oxadiazin-2-ones and Oxazolones through Regioselective Iodocyclization of Ynamides, Org. Lett. 2015, 17, 2510–2513. * He, G.; Chen, S.; Wang, Q.; Huang, H.; Zhang, Q.; Zhang, D.; Zhang, R.; Zhu, H*. Studies on copper(I)-catalyzed highly regio- and stereo-selective hydroboration of alkynamides, Org. Biomol. Chem. 2014, 12, 5945–5953. * He, G.; Zhang, Q.; Huang, H.; Chen, S.; Wang, Q.; Zhang, D.; Zhang, R.; Zhu, H*. Copper(I)-Catalyzed Highly Regio- and Stereoselective Boron Addition–Protonolysis of Alkynamides to give Alkenamides, Eur. J. Org. Chem. 2013, 2013, 6979–6989. * 何广科,陈山,马鸿飞,王强,朱红军*。 克莱森酯缩合反应中碱性试剂作用的探讨, 化学教育,2014, 35, 57–59.

专利、著作版权等

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